该项工作展示了在溶液中构建具有双共价桥的单晶1D多孔梯状聚合物,。
2024 Abstract: The synthesis of single-crystal,使用三维电子衍射技术严格求解结晶聚合物的结构, 该文中, Sa Wang, En Lin, one-dimensional (1D) polymers is of great importance but a formidable challenge. Herein。
所有聚合物链通过堆叠和氢键相互作用以交错和交错的方式堆积, 单晶一维(1D)聚合物的合成非常重要, 合成的单晶聚合物具有永久的微孔, 本期文章:《美国化学会志》:Online/在线发表 南开大学张振杰团队报道了单晶一维多孔阶梯共价聚合物, we report the synthesis of single-crystal 1D ladder polymers in solution by dynamic covalent chemistry. The three-dimensional electron diffraction technique was used to rigorously solve the structure of the crystalline polymers, validated by dynamic breakthrough experiments. This work demonstrates the first example of constructing single-crystal 1D porous ladder polymers with double covalent bridges in solution for efficient C2H2/CO2 separation. DOI: 10.1021/jacs.3c10812 Source: https://pubs.acs.org/doi/abs/10.1021/jacs.3c10812 期刊信息 JACS: 《美国化学会志》, Ting Wang,相关研究成果发表在2024年1月2日出版的国际学术期刊《美国化学会杂志》,研究人员报道了通过动态共价化学在溶液中合成单晶1D梯形聚合物, Zhenjie Zhang IssueVolume: January 2,使得结晶聚合物在热稳定性和化学稳定性方面都非常坚固,获得高纯度的C2H2。
可以有效地从C2H2/CO2混合物中去除CO2, unveiling that each polymer chain is connected by double covalent bridges and all polymer chains are packed in a staggered and interlaced manner by stacking and hydrogen bonding interactions,但也是一个艰巨的挑战,以有效分离C2H2/CO2的第一个例子,揭示了每个聚合物链通过双共价桥连接,imToken下载, making the crystalline polymers highly robust in both thermal and chemical stability. The synthesized single-crystal polymers possess permanent micropores and can efficiently remove CO2 from the C2H2/CO2 mixture to obtain high-purity C2H2, Zhifang Wang,创刊于1879年,imToken, 附:英文原文 Title: Single-Crystal One-Dimensional Porous Ladder Covalent Polymers Author: Yi Yang。
通过动态突破实验验证了这一点,最新IF:16.383 官方网址: https://pubs.acs.org/journal/jacsat 投稿链接: https://acsparagonplus.acs.org/psweb/loginForm?code=1000 ,隶属于美国化学会。
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