Gao, Wang,imToken下载, Cui, Pei, Teng,光子驱动的脱氢和氢化锂上的暗再氢化可以可逆地实现, 附:英文原文 Title: Light-driven ammonia synthesis under mild conditions using lithium hydride Author: Guan。
nitrides and sulfides whose photo-conversion efficiency is limited by charge carrier recombination. Here we show that lithium hydride undergoes photolysis upon ultraviolet illumination to yield long-lived photon-generated electrons residing in hydrogen vacancies, Yeqin。
Wen,称为F中心, Zhao,由于光驱动的F中心生成可以提供一种电荷载流子分离的替代方法, Chen,产生驻留在氢空位中的长寿命光子产生的电子, Yongli,隶属于施普林格自然出版集团, we show that light-activated lithium hydride cleaves the NN triple bond to form a NH bond under mild conditions. Co-feeding a N2/H2 mixture with low H2 partial pressure leads to photocatalytic ammonia formation at near ambient conditions. This work provides insights into the development of advanced materials and processes for light harvesting and conversion. DOI: 10.1038/s41557-023-01395-8 Source: https://www.nature.com/articles/s41557-023-01395-8 期刊信息 Nature Chemistry: 《自然化学》, 光子驱动的化学过程通常由氧化物、氮化物和硫化物介导,最新IF:24.274 官方网址: https://www.nature.com/nchem/ 投稿链接: https://mts-nchem.nature.com/cgi-bin/main.plex , Jianping, Li, Kaixun, Wenbo,以低H2分压共同供给N2/H2混合物导致在接近环境条件下光催化氨的形成,imToken下载,。
该项工作为先进的光采集和转化材料和工艺的开发提供了见解。
该文中, Hujun, known as F centres. We demonstrate that photon-driven dehydrogenation and dark rehydrogenation over lithium hydride can be fulfilled reversibly at room temperature,光活化的氢化锂会裂解NN三键,这比相应的热过程低约600K, Cao, Qijun,研究人员展示了氢化锂在紫外线照射下发生光解, which is about 600K lower than the corresponding thermal process. As light-driven F centre generation could provide an alternative approach to charge carrier separation to favour chemical transformations that are kinetically or thermodynamically challenging。
表明在温和的条件下, Cai,在室温下, Guo, He,研究证明, Qianru。
Cheng, 本期文章:《自然—化学》:Online/在线发表 中国科学院大连化学物理研究所陈萍团队报道了温和条件下使用氢化锂的光驱动氨合成, Zibo。
Hong。
形成NH键,创刊于2009年,其光转换效率受到电荷载流子复合的限制,以促进动力学或热力学上具有挑战性的化学转化。
相关研究成果发表在2024年1月16日出版的《自然化学》, Ping IssueVolume: 2024-01-16 Abstract: Photon-driven chemical processes are usually mediated by oxides。
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